Wave–particle duality . . .what its impact

Publicized early in the debate about whether light was composed of particles or waves, a wave-particle dual nature soon was found to be characteristic of electrons as well. The evidence for the description of light as waves was well established at the turn of the century when the photoelectric effect introduced firm evidence of a particle nature as well. On the other hand, the particle properties of electrons was well documented when the DeBroglie hypothesis and the subsequent experiments by Davisson and Germer established the wave nature of the electron.

At the close of the 19th century, the reductionism of atomic theory began to advance into the atom itself; determining, through physics, the nature of the atom and the operation of chemical reactions. Electricity, first thought to be a fluid, was now understood to consist of particles called electrons. This was first demonstrated by J. J. Thomson in 1897 when, using a cathode ray tube, he found that an electrical charge would travel across a vacuum (which would possess infinite resistance in classical theory). Since the vacuum offered no medium for an electric fluid to travel, this discovery could only be explained via a particle carrying a negative charge and moving through the vacuum. This electron flew in the face of classical electrodynamics, which had successfully treated electricity as a fluid for many years (leading to the invention of batteries, electric motors, dynamos, and arc lamps). More importantly, the intimate relation between electric charge and electromagnetism had been well documented following the discoveries of Michael Faraday and James Clerk Maxwell. Since electromagnetism was known to be a wave generated by a changing electric or magnetic field (a continuous, wave-like entity itself) an atomic/particle description of electricity and charge was a non sequitur. Furthermore, classical electrodynamics was not the only classical theory rendered incomplete.

Wave–particle duality is the concept that every elementary particle or quantic entity may be partly described in terms not only of particles, but also of waves. It expresses the inability of the classical concepts "particle" or "wave" to fully describe the behavior of quantum-scaleobjects. As Albert Einstein wrote: "It seems as though we must use sometimes the one theory and sometimes the other, while at times we may use either. We are faced with a new kind of difficulty. We have two contradictory pictures of reality; separately neither of them fully explains the phenomena of light, but together they do."

Through the work of Max Planck, Einstein, Louis de Broglie, Arthur Compton, Niels Bohr and many others, current scientific theory holds that all particles also have a wave nature (and vice versa). This phenomenon has been verified not only for elementary particles, but also for compound particles like atoms and even molecules. For macroscopic particles, because of their extremely short wavelengths, wave properties usually cannot be detected.

Although the use of the wave-particle duality has worked well in physics, the meaning or interpretation has not been satisfactorily resolved; see Interpretations of quantum mechanics.

Niels Bohr regarded the "duality paradox" as a fundamental or metaphysical fact of nature. A given kind of quantum object will exhibit sometimes wave, sometimes particle, character, in respectively different physical settings. He saw such duality as one aspect of the concept of complementarity. Bohr regarded renunciation of the cause-effect relation, or complementarity, of the space-time picture, as essential to the quantum mechanical account.

Werner Heisenberg considered the question further. He saw the duality as present for all quantic entities, but not quite in the usual quantum mechanical account considered by Bohr. He saw it in what is called second quantization, which generates an entirely new concept of fields which exist in ordinary space-time, causality still being visualizable. Classical field values (e.g. the electric and magnetic field strengths of Maxwell) are replaced by an entirely new kind of field value, as considered in quantum field theory. Turning the reasoning around, ordinary quantum mechanics can be deduced as a specialized consequence of quantum field theory

While Planck had solved the ultraviolet catastrophe by using atoms and a quantized electromagnetic field, most contemporary physicists agreed that Planck's "light quanta" represented only flaws in his model. A more-complete derivation of black body radiation would yield a fully continuous and 'wave-like' electromagnetic field with no quantization. However, in 1905 Albert Einstein took Planck's black body model to produce his solution to another outstanding problem of the day: the photoelectric effect, wherein electrons are emitted from atoms when they absorb energy from light. Since their discovery eight years previously, electrons had been studied in physics laboratories worldwide.

In 1902 Philipp Lenard discovered that the energy of these ejected electrons did not depend on the intensity of the incoming light, but instead on its frequency. So if one shines a little low-frequency light upon a metal, a few low energy electrons are ejected. If one now shines a very intense beam of low-frequency light upon the same metal, a whole slew of electrons are ejected; however they possess the same low energy, there are merely more of them. The more light there is, the more electrons are ejected. Whereas in order to get high energy electrons, one must illuminate the metal with high-frequency light. Like blackbody radiation, this was at odds with a theory invoking continuous transfer of energy between radiation and matter. However, it can still be explained using a fully classical description of light, as long as matter is quantum mechanical in nature.

If one used Planck's energy quanta, and demanded that electromagnetic radiation at a given frequency could only transfer energy to matter in integer multiples of an energy quantum hν, then the photoelectric effect could be explained very simply. Low-frequency light only ejects low-energy electrons because each electron is excited by the absorption of a single photon. Increasing the intensity of the low-frequency light (increasing the number of photons) only increases the number of excited electrons, not their energy, because the energy of each photon remains low. Only by increasing the frequency of the light, and thus increasing the energy of the photons, can one eject electrons with higher energy. Thus, using Planck's constant h to determine the energy of the photons based upon their frequency, the energy of ejected electrons should also increase linearly with frequency; the gradient of the line being Planck's constant. These results were not confirmed until 1915, when Robert Andrews Millikan, who had previously determined the charge of the electron, produced experimental results in perfect accord with Einstein's predictions. While the energy of ejected electrons reflected Planck's constant, the existence of photons was not explicitly proven until the discovery of the photon antibunching effect, of which a modern experiment can be performed in undergraduate-level labs. This phenomenon could only be explained via photons, and not through any semi-classical theory (which could alternatively explain the photoelectric effect). When Einstein received his Nobel Prizein 1921, it was not for his more difficult and mathematically laborious special and general relativity, but for the simple, yet totally revolutionary, suggestion of quantized light. Einstein's "light quanta" would not be called photons until 1925, but even in 1905 they represented the quintessential example of wave-particle duality. Electromagnetic radiation propagates following linear wave equations, but can only be emitted or absorbed as discrete elements, thus acting as a wave and a particle simultaneously.